{"id":10697,"date":"2024-06-29T01:44:39","date_gmt":"2024-06-29T01:44:39","guid":{"rendered":"https:\/\/haynesintl.com\/alloys\/%e6%ba%b6%e6%8e%a5%e3%81%a8%e8%a3%bd%e4%bd%9c\/descaling-and-pickling\/"},"modified":"2024-11-26T18:34:49","modified_gmt":"2024-11-26T18:34:49","slug":"%e3%82%b9%e3%82%b1%e3%83%bc%e3%83%ab%e9%99%a4%e5%8e%bb%e3%81%a8%e9%85%b8%e6%b4%97","status":"publish","type":"alloys","link":"https:\/\/haynesintl.com\/ja\/gokinrui\/%e6%ba%b6%e6%8e%a5%e3%81%a8%e8%a3%bd%e4%bd%9c\/%e3%82%b9%e3%82%b1%e3%83%bc%e3%83%ab%e9%99%a4%e5%8e%bb%e3%81%a8%e9%85%b8%e6%b4%97\/","title":{"rendered":"\u30b9\u30b1\u30fc\u30eb\u9664\u53bb\u3068\u9178\u6d17"},"content":{"rendered":"\n

Applicable to:<\/strong>
Corrosion-resistant Alloys<\/strong>
High-temperature Alloys<\/strong>
Wear & Corrosion-resistant Alloy<\/strong><\/p>\n\n\n\n

As a result of their inherent resistance to corrosion, the HAYNES\u00ae<\/sup> and HASTELLOY\u00ae<\/sup> alloys are generally inert to cold acid pickling solutions. Also, the oxide films that form on these alloys during heat treatment are more adherent than those that form on the stainless steels.<\/p>\n\n\n\n

The most effective descaling methods for the HAYNES\u00ae<\/sup> and HASTELLOY\u00ae<\/sup> alloys are immersion in molten caustic baths, followed by acid pickling at elevated temperatures.<\/p>\n\n\n\n

Three descaling methods have been used successfully with the HAYNES\u00ae<\/sup> and HASTELLOY\u00ae<\/sup> alloys, namely:<\/p>\n\n\n\n

    \n
  1. The VIRGO descaling salt bath process.<\/li>\n\n\n\n
  2. The sodium hydride reducing salt bath process.<\/li>\n\n\n\n
  3. The DGS oxidizing salt bath process.<\/li>\n<\/ol>\n\n\n\n

    The procedures associated with these methods are shown in the table below.<\/p>\n\n\n\n

    Descaling and Pickling Procedures<\/h3>\n\n\n\n
    \n \n\n \n \n \n \n \n \n \n \n \n \n
    \n - <\/th>\n \n VIRGO Descaling Salt Bath <\/th>\n \n Sodium Hydride Reducing Salt Bath <\/th>\n \n DGS Oxidizing Salt Bath <\/th>\n <\/tr>\n
    \n Descaling Bath <\/td>\n \n VIRGO Salt <\/td>\n \n Sodium Hydride <\/td>\n \n DGS Salt <\/td>\n <\/tr>\n
    \n Bath Temperature <\/td>\n \n 970\u00b0F (521\u00b0C) <\/td>\n \n 750\u00b0F-800\u00b0F (399\u00b0C-427\u00b0C) <\/td>\n \n 850\u00b0F-950\u00b0F (454\u00b0C-510\u00b0C) <\/td>\n <\/tr>\n
    \n Descaling Time <\/td>\n \n 1 to 3 minutes <\/td>\n \n 15 minutes <\/td>\n \n 2 to 10 minutes <\/td>\n <\/tr>\n
    \n Water Rinse Time <\/td>\n \n 1 to 2 minutes <\/td>\n \n 1 to 2 minutes <\/td>\n \n 1 to 5 minutes <\/td>\n <\/tr>\n
    \n Pickling Step 1 <\/td>\n \n 15-17% Sulfuric Acid+ 0.5-1% Hydrochloric Acid at 165\u00b0F (74\u00b0C) for 3 minutes* <\/td>\n \n 4-6% Potassium Permanganate+ 1-2% Sodium Hydroxide at 135\u00b0F-155\u00b0F (57\u00b0C-68\u00b0C) for 15 minutes* <\/td>\n \n 15-25% Nitric Acid+ 3-5% Hydrofluoric Acid at 130\u00b0F-150\u00b0F (54\u00b0C-66\u00b0C) for 10 to 20 minutes <\/td>\n <\/tr>\n
    \n Pickling Step 2 <\/td>\n \n 7-8% Nitric Acid+ 3-4% Hydrofluoric Acid at 125\u00b0F-160\u00b0F (52\u00b0C-71\u00b0C) for 25 minutes <\/td>\n \n 8-12% Nitric Acid+ 2-3% Hydrofluoric Acid at 125\u00b0F-160\u00b0F (52\u00b0C-71\u00b0C) for 15 minutes <\/td>\n \n No Second Step <\/td>\n <\/tr>\n
    \n Final Water Rinse <\/td>\n \n 3 minutes or Steam Spray <\/td>\n \n Dip <\/td>\n \n Dip and Steam Spray <\/td>\n <\/tr>\n
    \n Descaling Bath <\/td>\n \n VIRGO Salt <\/td>\n \n Sodium Hydride <\/td>\n \n DGS Salt <\/td>\n <\/tr>\n
    \n Bath Temperature <\/td>\n \n 970\u00b0F (521\u00b0C) <\/td>\n \n 750\u00b0F-800\u00b0F (399\u00b0C-427\u00b0C) <\/td>\n \n 850\u00b0F-950\u00b0F (454\u00b0C-510\u00b0C) <\/td>\n <\/tr>\n <\/table>\n<\/div>